Inorganic–Organic lead halide materials have been recognized as potential high-energy X-ray detectors because of their high quantum efficiencies and radiation hardness. Surprisingly little is known about whether the same is true for extreme-ultraviolet (XUV) radiation, despite applications in nuclear fusion research and astrophysics. We used a table-top high-harmonic generation setup in the XUV range between 20 and 45 eV to photoexcite methylammonium lead bromide (MAPbBr3) and measure its scintillation properties. The strong absorbance combined with multiple carriers being excited per photon yield a very high carrier density at the surface, triggering photobleaching reactions that rapidly reduce the emission intensity. Concurrent to and in spite of this photobleaching, a recovery of the emission intensity as a function of dose was observed. X-ray photoelectron spectroscopy and X-ray diffraction measurements of XUV-exposed and unexposed areas show that this recovery is caused by XUV-induced oxidation of MAPbBr3, which removes trap states that normally quench emission, thus counteracting the rapid photobleaching caused by the extremely high carrier densities. Furthermore, it was found that preoxidizing the sample with ozone was able to prolong and improve this intensity recovery, highlighting the impact of surface passivation on the scintillation properties of perovskite materials in the XUV range.

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Dutch Ministry of Economic Affairs, TKI , NWO VIDI , EPSRC , NWO VENI
J. Phys. Chem. C
Materials & Surface Science for EUV Lithography

van der Geest, M., McGovern, L., van Vliet, S., Zwaan, H., Grimaldi, G., de Boer, J., … Kraus, P. (2022). Extreme-Ultraviolet Excited Scintillation of Methylammonium Lead Bromide Perovskites. J. Phys. Chem. C, 126(30), 12554–12562. doi:10.1021/acs.jpcc.2c02400