We report on singular jets in a free-falling liquid tin droplet following nanosecond laser-pulse impact. Following impact, the droplet (with diameter 0=50 or 70µ⁢m ) undergoes rapid radial expansion and subsequent retraction, resulting in the formation of an axisymmetric jet. Using numerical simulations in tandem with our experiments, we reveal that a delicate interplay between radial flow and the curvature of the retracting droplet governs jet formation. The resulting dynamics is characterized using the impact Weber number, We (in the experiments 2≲We≲16 ), and a pressure width, W (typically 1≲≲2 ), which describes the angular distribution over the droplet surface of the instantaneous pressure impulse exerted by the transient laser-produced plasma. For values We<10 , the droplet presents a pronounced curvature during the retraction, leading to the formation of a cavity. The collapse of such a cavity leads to a singular jet that greatly enhances the jetting velocity up to ten times the impact propulsion velocity, an effect that narrowly peaks around We∼6–8 , reminiscent of singular jets in droplet-solid impact. We identify a further sensitivity of the jet velocity enhancement on the pressure width W and capture the dynamics in a phase diagram connecting the various deformation morphologies with jet velocity.